Carbocraft

Silica Gel & PVPP

CARBOCRAFT is an active proponent of beer stabilization! Not only does the CARBOCRAFT TEAM continually support the beer industry by stimulating demand for the precious golden liquid through a steady consumption of it, CARBOCRAFT also contributes to bringing about an optimum and sustained clarity of the tasty beverage, through the supply of highly efficient clarifiers and stabilizers to the brewing fraternity! CARBOCRAFT is privileged to be working in close partnership with international market leader Stabifix Brauerei-Technik GmbH & Co. KG!

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LEADING TECHNOLOGY IN BEER STABILISATION AND CLARIFICATION FOR MORE THAN 50 YEARS

STABIFIX has stood for decades as the method of choice to make beer brilliant and stable. STABIFIX practically invented protein stabilisation with silica gels more than 50 years ago and has been perfecting the process ever since. When targeting long term clarity, brewers want to avoid one-sided excessive treatments. The aim is a well-balanced stabilisation process which protects valuable beer components while removing critical fractions as is necessary. Therefore, STABIFIX developed STABICLEAR PVPP to adsorb haze-reactive polyphenols, commonly used in combination with STABIFIX and STABIQUICK silica gels, to ensure the best possible stabilisation and clarification results.

For many years, our new and innovative product, STABISOL has been adding value to brews around the world! STABISOL accelerates particle formation and removal, thus supporting faster brewing by debottlenecking critical steps in the brewing process. Highly compelling advantages await the brewer when using STABISOL during boiling, racking and filtration, namely: – a brighter wort, reduction of particles in pitching wort, faster fermentation, less sediment in fermenters, faster sedimentation in maturation tank, brighter unfiltered beer, better beer filterability, coupled with longer filter runs!

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Silica gels play a crucial role in beer stabilization by controlling haze formation and extending the shelf life of the beer. They are often used as a fining agent to improve beer clarity and stability. The main function of silica gels is to remove certain compounds such as proteins and polyphenols that could cause hazy appearances or off-flavours in beer. When beer is chilled or subjected to temperature fluctuations, these compounds can coagulate and cause a haze to form. Silica gels help to bind and remove these particles, resulting in clearer, more stable beer. The porous nature of silica gels, with a large surface area, allows them to efficiently adsorb proteins and polyphenols, contributing to the beer’s flavour stability. By adsorbing these compounds, silica gels help maintain a consistent flavour profile and extend the shelf life of the beer.

PVPP, or polyvinylpolypyrrolidone, is a synthetic polymer commonly used as a fining agent in the clarification process of both beer and wine. In beer clarification, PVPP plays a crucial role in reducing haze and stabilizing the final product. It specifically targets polyphenols that can cause haziness in beer. Polyphenols are compounds derived from malt, hops, and other ingredients used in brewing. They can form complexes with proteins, resulting in turbidity and haze formation, negatively impacting the beer’s appearance and quality. Similarly, in wine clarification, PVPP targets and eliminates various polyphenols, including tannins and anthocyanins, which can lead to haze formation. These compounds may negatively affect the wine’s clarity, colour, and stability. The addition of PVPP helps remove these polyphenols, reducing haziness and improving the overall quality of the wine.

Silica gel also plays a crucial role in the process of edible oil refining, specifically in the step known as bleaching. Edible oil refining is a process that aims to remove impurities, colorants, odours, and other undesirable substances present in crude vegetable oil, resulting in a more refined and higher-quality end product. During the bleaching process, silica gel is used as an adsorbent to remove various impurities from the oil. It acts as a filtration agent that selectively adsorbs unwanted components, thereby improving the colour, taste, and stability of the oil. The impurities in the crude oil that are targeted by silica gel include pigments, trace metals, phospholipids, soaps, and other organic compounds. These impurities can contribute to the oil’s undesirable colour, off-flavours, and reduced shelf life. Silica gel’s high surface area and porous structure make it an excellent adsorbent. It has a strong affinity for a wide range of impurities, allowing it to efficiently remove them from the oil. The impurities in the oil are attracted to the surface of the silica gel particles and adhere to them through adsorption. This process effectively reduces the concentration of the impurities, resulting in a clarified and refined oil. The bleaching process typically involves mixing the crude oil with a specific amount of silica gel, followed by agitation and heat treatment. This helps facilitate the adsorption of impurities onto the silica gel particles. Afterward, the mixture is filtered to separate the silica gel along with the adsorbed impurities, leaving behind the refined oil.

 

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OPTIMUM BEER STABILISATION AND CLARIFICATION

Brewing is a complex process that involves intricate biochemistry and physical chemistry. Colloidal haze, or non-biological haze, forms when haze-sensitive proteins and polyphenols combine, or when larger molecules create “complexes” that cause visual turbidity. This leads to a decline in the physical-chemical stability and quality of the beer over time, particularly if storage and transport conditions are suboptimal.

Haze-active proteins and polypeptides derived from barley proteins (hordeins) are involved in protein-polyphenol complexation. These proteins have proline-rich regions that form binding sites for the proline recognition sites on polyphenols. Colloidal haze can manifest as chill haze, occurring at low temperatures due to weak hydrogen bonds between proteins and small polymerized polyphenols, which tend to disappear when the beer is warmed. Alternatively, colloidal haze can form permanent haze, resulting from stronger covalent bonds between haze-sensitive proteins and further polymerized polyphenols, creating larger complexed molecules that do not dissolve when the beer is warmed. The need for colloidal haze stabilization in beer depends on the required shelf life and storage conditions of the packaged beer.

STABIFIX PRODUCTS MEET INTERNATIONAL FOOD STANDARDS

STABIFIX silica gels, silica sols, PVPP, and enzymes adhere to international food safety standards as approved processing aids. They are insoluble in wort and beer and are entirely removed through sedimentation (natural settling) and/or filtration, ensuring no reaction products remain in the beer. Therefore, if the beer does not look and taste as it should, the use of silica gel and/or PVPP is certainly not to blame, but rather the inadequate use of these highly efficient process aids!

Many STABIFIX stabilization products are compatible with kieselguhr and beer membrane filters. Additionally, STABIFIX silica gels, silica sols, and PVPP comply with the German Beer Purity Law.

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STABIFIX PRODUCT RANGE – FIXED BEER STABILITY

STABIFIX silica-based stabilizers and clarifiers are highly effective in adsorbing haze-reactive proteins. The adsorption capacity of each product is determined by its structure, pore volume, and moisture content.

STABIFIX® SUPER
  • A xerogel for optimising filtration.
STABIQUICK® STRONG
  • A high performing xerogel that adsorbs haze-active proteins and maximizes colloidal stability.

STABIFIX® NT
  • A xerogel with a pore matrix for selective adsorption. 

STABIFIX® EXTRA + STABIQUICK® SELECT
  • Hydrated xerogels that combine the advantages of both a xerogel and a hydrogel. The availability of each product is country dependent.

STABIQUICK® SEDI
  • A xerogel with extreme stabilisation properties. It is also applied for pre-clarification. Now bentonite-free. Not suitable for the filter. 

     

STABISOL® 300
  • An in-tank beer clarifier that can be used for pre-clarification, clarification and for optimising filtration. 

STABIFIX® W/WMF
  • A hydrogel for optimal low dust stabilisation and filtration performance. For kieselguhr and membrane filters.

STABICLEAR® P
  • A PVPP with a high affinity for haze-active polyphenols for optimizing the colloidal stability of beer. Highly recommended for use in combination with STABIFIX silica-based products.

STABICLEAR® TFS
  • A fast-dissolving hydrolysable gallotannin from a natural plant source offers improved colloidal and flavor stability. It selectively binds haze-reactive proteins and, due to its high purity, does not affect the flavor, foam, or color of the beer. Additionally, gallotannins are known for their metal-chelating properties.
STABIFIX ENZYMES
  • The new STABIFIX enzymes for clarification and improved filtration: reduce haze, improve beer filterability, and greatly enhance colloidal stability. Furthermore, by combining PEPfix® and/or FLOWfix® with STABIFIX silica gels, colloidal stability increases significantly.

PEPfix®
  • A prolyl oligopeptidase (also known as prolyl endopeptidase) hydrolyzes proline-rich proteins, primarily at the carboxyl site, enhancing colloidal stability by disrupting protein-polyphenol interactions. PEPfix® can also be used to produce gluten-free beer. Colloidal stability significantly improves when PEPfix® is used in combination with STABIFIX silica gel. This combined application allows for a substantial reduction in enzyme dosage rates, leading to considerably lower costs in use.

FLOWfix®
  • FLOWfix® is a high-performing blend of glucanase and arabinoxylanase that breaks down major cell wall components. It targets β-glucans and xylans, including water-soluble arabinoxylans, to reduce wort and beer viscosity, resulting in faster wort separation and beer filtration, higher throughput, and haze reduction. FLOWfix® provides brewers with greater flexibility in raw material choices, allowing for easy adjustment of adjunct ratios. Additionally, the thermostability of FLOWfix® positively impacts sustainability.
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CARBOCRAFT is passionate about beer and beer stability! Let us help you to produce a crystal-clear beer, that will stay that way for eternity, well, almost anyway. Please contact our expert Sales Technicians who can advise you on just the right STABIFIX grade you need, to put a sparkle in your beer!